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Doctor Olds
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[Tech] Synthetic oil clarifications

Either buy Amsoil, Mobil1 or Royal Purple synthetics *ONLY*. The others are not made from PAO Synthetic stocks even though they say Synthetic on the bottle it is Petroleum based in the bottle, not PAO (PolyAlphaOlefin) base stock derived.

»www.oilsandlube.com/
quote:
AMSOIL is proven to be the best! In fact up until about 10-15 years ago many of these manufacturers never even had a synthetic (except Mobil1). They were too busy trying to debunk the benefits of synthetics to the average consumer! Now, technology and competition has forced every major oil manufacturer to have a synthetic, but yet not a single one even comes close to offering the protection that AMSOIL does. In fact, the Castrol Syntec isn't even a 100% pure synthetic. That's right...read on........

CASTROL AND MOBIL GO TO COURT TO BATTLE IT OUT:

Recently, Mobil accused Castrol of reformulating its synthetic by substituting other basestocks in place of its synthetic polyalphaolefins (PAO's). Castrol Syntec is a hydrocracked oil. That's right, Castrol has replaced the PAO synthetic base stock with hydroisomerized petroleum base stock. Hydrocracking, as it's called, is the highest level of petroleum refining. Castrol isn't even a true synthetic yet Castrol ended up winning the battle when the National Advertising Division of the Council of Better Business Bureaus ruled that Castrol could still market its oil as "synthetic" despite their new formulation. Basically, they expanded the definition of synthetics to include Group III hydroprocessed petroleum oil. This high profile case took place because synthetics are recognized as the market's best hope for growth. Synthetic oil sales have outpaced petroleum oil sales by a wide margin and the gap continues to widen every year. Consumers are getting smarter and demand the best for their vehicles! Read the full story on the Castrol debacle in our informative articles section. Additionally, just as soon as Castrol won this battle, several other major oil companies jumped in and came up with hydroprocessed motor oils of their own and labeled these products to be "100% synthetic", when they still are primarily Group III hydroprocessed petroleum oils!
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Re: [Tech] Synthetic oil and oil life monitor

I can't argue any of this based on a detailed understanding of the molecular structure of complex hydrocarbons, but ...

1. The quotes you're citing are pretty clearly biased by one manufacturer. Their motives can't be altruistic.

2. Your sources note that two respected industry groups agreed that the products are effectively equivalent and therefore supported the use of the term synthetic.

I'm reading this, thinking this sounds a lot like a fight over which gasoline is better than the others. I doubt anyone using Syntec per the manufacturer's instructions and per the recommendation of their car maker will have poorer results than someone who uses Mobil 1 under the same conditions.

Seems to me that one camp is trying to do exactly what they accuse the other of doing - creating an inaccurate perception in the minds of the consumer.


Doctor Olds
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said by No_Strings See Profile :

I can't argue any of this based on a detailed understanding of the molecular structure of complex hydrocarbons, but ...
I look at it this way, either it is made from Group IV Base Stock making it a Synthetic Oil with uniform hydrocarbon molecules or it is made from a Group I, II, or III Base Stock making it a Conventional Petroleum Oil with broken, uneven length hydrocarbon molecules that have reduced load protection along with reduced shear resistance (as high as 8 times less protection to as as low as 5 times less protection).

I think the definition is self explanatory, either it is made from Synthetic material (Group IV base oil) or it is made from Petroleum material (Group I, II, or III base oils).

»en.wikipedia.org/wiki/Synthetic_oil
quote:
Synthetic oil is a lubricant consisting of chemical compounds which are artificially made (synthesized) from compounds other than crude oil (petroleum). Synthetic oil is used as a substitute for lubricant refined from petroleum, because it generally provides superior mechanical and chemical properties than those found in traditional mineral oils.
Further down in the above link
quote:
A Synthetic or Synthesized material is one that is produced by combining or building individual units into a unified entry. Synthetic base stocks as described above are man-made and tailored to have a controlled molecular structure with predictable properties, unlike mineral base oils which are complex mixtures of naturally occurring hydrocarbons
And the bullet point (showing that there was somthing under the table or underhanded in the allowing of a revision for any Group III being now called synthetic)
quote:
Group III based lubricants are not allowed to be marketed as "synthetic" in any market outside of the USA.
»en.wikipedia.org/wiki/Crude_oil Also Known As »en.wikipedia.org/wiki/Petroleum
quote:
Petroleum is a mixture of a very large number of different hydrocarbons; the most commonly found molecules are alkanes (linear or branched), cycloalkanes, aromatic hydrocarbons, or more complicated chemicals like asphaltenes. Each petroleum variety has a unique mix of molecules, which define its physical and chemical properties, like color and viscosity.
Check out these test results.

Comparative Motor Oil Testing
»www.amsoil.com/comparison/motor-oil.aspx

HTH
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said by Doctor Olds See Profile :

Group III based lubricants are not allowed to be marketed as "synthetic" in any market outside of the USA.
Hmm.. that explains why Castrol has "Not for sale outside USA" on their labels.
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No_Strings
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reply to Doctor Olds
The last link (on Amsoil's site, so no surprise) compares its product against syn blends and dino oil. Seems like a pretty useless comparison.


Doctor Olds
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said by No_Strings See Profile :

The last link (on Amsoil's site, so no surprise) compares its product against syn blends and dino oil. Seems like a pretty useless comparison.
Nope. Full Synthetics, Blended Synthetics and petroleum based oils were equally represented.

»www.amsoil.com/comparison/motor-oil.aspx
quote:
AMSOIL Synthetic 10W-30 Motor Oil (ATM) and 10 competing conventional, synthetic and synthetic blend 10W-30 motor oils were subjected to a series of motor oil tests. The competing oils included petroleum-based Castrol GTX, Chevron Supreme, Havoline, Formula Shell and Pennzoil, as well as synthetic-blends Trop Artic and Motorcraft, and full-synthetic Pennzoil Platinum, Quaker State Advanced Full Synthetic and Mobil 1 Extended Performance.
Amsoil and Mobil1 tend to be the top 2 Synthetics in the field with Redline, Royal Purple and a few others that are not too far behind filling out the rest of the field.

They Say Nothing Outperforms Mobil1--WRONG!
»texassynthetics.com/articles/mobile1.html

Regards,

Doctor Olds
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No_Strings
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Castrol GTX is not advertised as synthetic on their web site. Why not compare against Syntec as an example?

Again, it all looks like card-stacking - a tried and true propaganda technique, but not science.


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said by No_Strings See Profile :

Castrol GTX is not advertised as synthetic on their web site. Why not compare against Syntec as an example?
Why? Syntec has not been a true Synthetic since 2000/2001 when they stopped making it out of PAO Synthetic Based Stocks and now only use Conventional Petroleum base stock instead so why bother when there are other true Synthetics made from PAO Base Stocks to compare against. Were the other three true Synthetics that are real PAO derived Base Stock Synthetics not good enough somehow? I mean they did test Amsoil Synthetic against Mobil1 Synthetic, Pennzoil Platinum Synthetic, and Quaker State Advanced Full Synthetic (all PAO base stock oils).

The Motor Oil Bible has these tidbits to digest (available here):

said by The Motor Oil Bible :
BASE FLUIDS (BASESTOCKS)

There are two main types of basestocks, petroleum and synthetic. Petroleum basestocks are a purified form of crude oil and have been used as the base for automotive lubricants since motor oils were first being developed.

Synthetic basestocks, on the other hand, are chemically engineered in a lab specifically for the purpose of lubrication. They are engineered from pure compounds that contain no contaminants which must be removed via purification. Synthetic basestocks have been around since the early 1900's but were not widely used in automotive type applications until the 70's.
said by The Motor Oil Bible :
PSEUDO-SYNTHETIC BASESTOCKS

There are some petroleum lubricants available on the market that are so pure and refined, they can now be passed off as synthetics. They are not made from true synthetic basestocks (at least not in the way that synthetics have traditionally been defined), but they have so little in common with traditional petroleum basestocks, it is really somewhat silly to classify them as merely petroleum lubricants.

Petroleum lubricant basestocks can be put through a super-extreme refining process called hydrocracking. In some cases, as in the case of one particular name-brand "synthetic" oil, these highly refined petroleum basestocks can actually be termed and sold as "synthetic" (Only in the USA). It is completely legal for lubricants manufacturers to label these oils as "synthetic".

These are extremely high performance petroleum basestocks, but they are not truly synthetic the way that most people understand the term and will not necessarily perform to the same level as a premium synthetic oil.

Hydrocracking involves changing the actual structure of many of the lubricant basestock molecules by breaking and fragmenting different molecular structures into far more stable ones.
said by The Motor Oil Bible :
SYNTHETIC BASESTOCKS

Synthetic lubricant basestocks have very little in common with their petroleum "cousins". They are used for a similar purpose. But, while one is designed specifically for the purpose of lubrication, the other has been simply transformed into something that will adequately do the job.

In fact, the relationship between these two basestock types would be similar to the relationship between a big rock and a hammer. Both can be used to drive nails, but one will be far more effective than the other. A hammer which is designed for driving nails will do so much more efficiently than will a rock.

In addition, the hammer will be able to drive nail after nail without any significant loss in its integrity. The quality of the hammer will degrade very little over time. However, the rock will easily be chipped and cracked when used to pound nails. In fact, you would probably find that after only a few dozen nails, you would need to go find a new rock to pound nails with.

You see, the rock was not designed to pound nails. Of course, you could fashion it into something that looked like a hammer if you like, but it's still a rock. It will work in a pinch, but it is not the right tool for the job. But, along comes "Nail Drivers Inc." with a novel idea. They decide to first determine what the qualities of a good "nail driver" would be. Then they fashion a tool that is specifically designed to have these qualities.

Doesn't it make sense that the new tool will accomplish the job far better than the old rock? The same is true of a synthetic oil when compared to a petroleum oil.
said by The Motor Oil Bible :
Synthetic vs. Petroleum

Oil is the lifeblood of your vehicle's engine. Without motor oil, there is little likelihood that any of your vehicles would make it past the end of your street each morning. For decades conventional petroleum oils have been providing adequate protection for all of our vehicles.

Notice the key word here: adequate. Petroleum oils, for the most part, have done an adequate job of protecting our engines from break down. If you change it often enough, you can be relatively sure that your car will last 100,000 to 150,000 miles without a serious engine problem - maybe even longer.

My question is this: Why are you settling for adequate when something better has been available for about 30 years? Do you ask your mechanic to simply keep your vehicle from breaking down, or do you want him/her to keep it running in tip-top shape? The fact that you are reading this book suggests the latter.

It is perfectly reasonable to expect top performance from your vehicles. You are certainly paying for it. It's tough to buy a vehicle for less than $15,000 to $20,000 anymore. That's a great deal of money to shell out for adequate performance.

Today's engines are built for better performance, and, although petroleum oils are designed for better protection and performance today than they were 10 or 20 years ago, there is only so much that can be done. Today's engines need high performance lubricants, and synthetics are the only ones that fit the bill.

WHY PETROLEUM OILS ARE INSUFFICIENT

Conventional petroleum oils are insufficient for use in today's vehicles primarily because they are manufactured from a refined substance, as was discussed in Chapter 2. Petroleum oil basestocks contain paraffins (wax), sulfur, nitrogen, oxygen, water, salts and certain metals. All of these contaminants must be refined out of the basestock in order for it to be useful for use within a lubricant.

Unfortunately, no refining process is perfect. Impurities will always remain when any refining process is done. It simply isn't economical to continue to refine the oil again and again to remove more impurities. If this was done, petroleum oils would cost as much as synthetic oils do.

Thus, there are many components of petroleum oil basestocks which are completely unnecessary for protecting your engine. They do absolutely nothing to enhance the lubrication properties of the oil. In fact, most of these contaminants are actually harmful to your oil AND your engine.
said by No_Strings See Profile :

Again, it all looks like card-stacking - a tried and true propaganda technique, but not science.
They tested 10 competing oils where 4 were Full True Synthetics, 5 were Conventional Petroleum and 2 were Synthetic Blends so that is far, far away from card stacking in any way, shape or form. You try to make it sound like Amsoil was the only Synthetic Oil tested period and that obviously was not the case with 4 Synthetics being compared in fact. The results clearly show the superior oil and it is a PAO Stock Synthetic.

HTH
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Re: [Tech] Synthetic oil clarifications

I use Mobil1 for now but I heard it changed a few years ago and is less of a true synthetic oil now, not sure if it's true or what that means exactly.

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Doctor Olds
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said by Vamp See Profile :

I use Mobil1 for now but I heard it changed a few years ago and is less of a true synthetic oil now, not sure if it's true or what that means exactly.

Mobil1 is still PAO base stock on their full synthetic. Now their synthetic blends do have other petroleum base stocks mixed so don't buy blends, but unlike Castrol Syntec and a few others, Mobil1 is a true PAO synthetic instead of now being made from regular Petroleum base stock aka crude oil and is misleadingly called a synthetic when it isn't. Read the story here.
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1 edit
reply to Doctor Olds
While I will agree that synthetic oils have certain pluses over conventional oils, I challenge any and all to show me unbiased proof that synthetic oil can extend engine life as compared to petroleum based engine oils.

I say the proof does not exist

Prove me wrong, please. I've been looking for the proof for over 30 years.

Remember, I said unbiased.


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I'm with you here Grumpy. I have a friend who has almost 300,000 miles on his 3.0 L Toyota pickup. You know the 3 Liter that was made famous for blowing head gaskets at an early age. He had the gaskets done at about 100,000 miles. Now with nearly 300,000 (it will be 300,000 at his next oil change) this vehicle has NEVER had any synthetic oil in it.

I have and never will waste my money on synthetic oil for a normal driven vehicle.
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said by TheHarvester See Profile :

I have and never will waste my money on synthetic oil for a normal driven vehicle.
Likewise.
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reply to Doctor Olds
Good reading about oil (and stuff) here:

»www.bobistheoilguy.com/forums/ubbthreads.php

There was a thread there a year or so back which said that Pennzoil Platinum was about the best "synthetic" oil one could buy besides Amsoil.


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said by Grumpy See Profile :

While I will agree that synthetic oils have certain pluses over conventional oils, I challenge any and all to show me unbiased proof that synthetic oil can extend engine life as compared to petroleum based engine oils.

I say the proof does not exist

Prove me wrong, please. I've been looking for the proof for over 30 years.

Remember, I said unbiased.
I think you are confused.

Synthetics and proper filtration do not make engines last longer; they make the oil last longer in service with no increase in wear over the extended intervals. The only way to extend the life of your engine is to use a properly designed maintenance routine. That works the same with both types, but you have much shorter change intervals with conventional oils that you don't have with synthetics.

Anyway, why didn't you buy two identical cars 30 Years ago and drive them identical with one using synthetics and one using conventional oils (and use oil analysis to determine proper change intervals for both). You could now be giving a 30 Year report today.
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reply to Grumpy
said by Grumpy See Profile :

While I will agree that synthetic oils have certain pluses over conventional oils, I challenge any and all to show me unbiased proof that synthetic oil can extend engine life as compared to petroleum based engine oils.

I say the proof does not exist

Prove me wrong, please. I've been looking for the proof for over 30 years.

Remember, I said unbiased.
I can't provide you proof... only a testimonial. I have a 1984 Ford Ranger with a 2.8 engine. It has been driven ever since it was new (handed down to me from my dad). It has only had Mobil1 oil in it. Ever. It currently has 500,000+ miles on it. I regularly take the valve covers off to adjust valve lash and there is only a slight tarnish on the springs and the underside of the valve covers.

I recently had the oil pan gasket replaced and got a chance to inspect the main bearings and the crank. Again, no build up. In fact, it looked practically new (observation only, not measured).

Several years ago I had to replace the head gasket and got a chance to inspect the cylinders. This time I did measure them. All 6 cylinders were still within factory spec with only a slight showing of ring wear. No need for a rebuild.

I also have a '94 F150 5.0L that only has 80K miles on it. I bought it from a guy who swore by Quaker state. He claimed that he religiously did oil changes every 3,000 miles and had records to prove it.

When I bought the truck from him I had to replace the oil pan gasket to fix a leak. The oil pan was covered in sludge. Even though the oil looked good, there was a relatively thick coating of sludge at the bottom of the pan when I ran my finger through it. The valve covers were the same. Coated. There was black carbon buildup on the inside of the oil cap.

I did a motor flush on it and switched it over to Mobil1. I drive the same route from home to work with the cruise control on, no stop signs or redlights on a straight highway. It is a very consistent commute. I usually am home from work within the minute each night. In the months before I did my first oil change (still was running Quaker State), I averaged 14.5 mpg. After changing to Mobil1 I now average 16.2 mpg.

I've driven it now for 2 years with synthetic oil in it and there is no more accumulating buildup in either the oil pan (inspected at oil changes) or the valve cover (looking through the fill port).

I've seen live demonstrations of synthetic vs conventional oil performance. Simply put, conventional oil breaks down like burned butter under normal engine temperatures. Synthetic oil does not.
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reply to Doctor Olds
Mobil 1 was reformulated with highly processed Group III base mineral oils. The Mobil 1 EP may still be PAO based, however.

Here's Mobil's answer to a Group III question: »https://www.mobiloil.com/USA-English/Mot···ils.aspx

Personally, I think that synthetic oils are better than conventional oils, but for most people they are not worth the price difference for the minuscule benefit they may provide over conventional oils, or blends.
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Some argue that with synthetic oils you can do fewer oil changes since it breaks down less... With fewer oil changes, you get close to your money back.
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aurgathor

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Yes, I'm fully aware of those arguments. But I can easily do 10k miles on a conventional oil (lots of hwy miles) so why bother with synthetic?

To get really high mileage out of oil, one would need a bypass filter and oil analysis once in a while, and those would more or less negate the possible savings on passenger vehicles.

Synthetic and boutique oils do have their own place -- either very high or very low temperatures, or racing engines, just to name some. But IMHO, it would most likely be a waste of money in my mostly stock 351W.

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Doctor Olds
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said by aurgathor See Profile :

Yes, I'm fully aware of those arguments. But I can easily do 10k miles on a conventional oil (lots of hwy miles) so why bother with synthetic?
Because you can go up to 35K with your mostly highway driving with PAO Synthetics and with changing only the filter at the intervals that the manufacturer recommends for conventional oil use. Plus your costs would not increase, but most likely it would be either close or possibly show a savings AND you are reducing your carbon footprint significantly along with reducing your waste oil production by 3 times - that's a big change - pardon pun. If your regular change interval is every 10K, then you would be at 3 filters replaced (1st at 10K, 2nd at 20K, 3rd at 30K) until it was time to fully drain and replace the PAO Synthetic oil at 35K with a new filter at that point. It actually saves you time due to the extended drain intervals while keeping the engine fully protected. You would want one oil analysis to see what 355K looked like and once you get the evidence that wear was not increased/no damage was done/oil still had life you wouldn't need to continue with future repeated multiple tests after the initial baseline is seen.

said by aurgathor See Profile :

To get really high mileage out of oil, one would need a bypass filter and oil analysis once in a while, and those would more or less negate the possible savings on passenger vehicles.
Negative, as the bypass is for never changing the oil and only topping it out and changing the filters on a schedule instead. for regular use, change the oil filter between the extended drain interval like you would on a conventional oil, but change the oil on the synthetic interval topping off the engine to replace the lost oil from the filter change. You can go up to 35K drain intervals on highway driving that way when using a PAO synthetics.
said by aurgathor See Profile :

Synthetic and boutique oils do have their own place -- either very high or very low temperatures, or racing engines, just to name some. But IMHO, it would most likely be a waste of money in my mostly stock 351W.
That explains the 40+ non-racing vehicles that come with Mobil1 as the Factory fill oil. Since they are not selling race cars and exotics there must be another reason the Manufacturers think that from day one Synthetics will perform better than Conventional Oils in their vehicles. These are the same manufacturers that loos at cost per unit when building a car which is why there is so much plastic and other cheaper materials instead of stainless steel and highest quality materials.

Boutique oils? Are you talking about massage parlors all of a sudden now?

With extended drain intervals you will have fewer oil changes, long term savings and convenience from the extra free time .
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